The game I play 90% of the time is Fallout 4 and I know that's in VR now. The bundle also has Skyrim which looks really good and I've never played before. I may spend the money on that instead of more money on a laptop that I don't really need at the moment.
If you have something you want to play in VR and there is a decent deal on a bundle go for it. As someone who has already invested in VR I would love to see more games like Fallout add in the support. My only problem with Fallout 4 VR is that they made it a separate $60 purchase on Steam even though I already own the game and season pass. Same for Doom and Skyrim. If your PSVR bundle includes those that won't be an issue for you.
I'm not trying to turn you off VR because when it is done well it truly is an amazing experience. Just have a realistic expectation of what is available before you invest in it. Also, buy Superhot VR. It is easily the best VR game I have played.