Knife edge refraction.
The following is copied from the Wikipedia article on radio propagation.
Knife-Edge diffraction is the propagation mode where radio waves are bent around sharp edges. For example, this mode is used to send radio signals over a mountain range when a line-of-sight path is not available. However, the angle cannot be too sharp or the signal will not diffract. The diffraction mode requires increased signal strength, so higher power or better antennas will be needed than for an equivalent line-of-sight path.
Diffraction depends on the relationship between the wavelength and the size of the obstacle. In other words, the size of the obstacle in wavelengths. Lower frequencies diffract around large smooth obstacles such as hills more easily. For example, in many cases where VHF (or higher frequency) communication is not possible due to shadowing by a hill, one finds that it is still possible to communicate using the upper part of the HF band where the surface wave is of little use.
