I have a 2nd 32.0 remote for TV2 upstairs. I just followed the normal procedure: Press menu twice on TV1 remote to bring up Sys Info. Then hold/press and release SAT button on TV2 remote.
Are you intending to use it as TV2 remote? If so make sure to change the mode to "2" at the bottom of the remote and try again. The default shipped remotes are set as mode "1".