SEC won't want them, as it would require taking UVa as well.
The issue of VT and UVA from the last ACC expansion to a possible VT going to the SEC won't be hampered by UVA in anyway nor a past Gov that is no longer in office. VT wants to move they will but they won't - very happy and content with staying in the ACC and I don't blame them one bit as they would have to fight for TV time vs right now VT is covered nationally just about every weekend with a nice ESPN/ACC contract (which is to be negotiated due to the recent additions).