"The angle of incidence is equal to the angle of reflection."
That, of course, is true for a flat mirror, or for the 'dot' mirror that you construct a (one) ray on.
For the whole of all the offset rays to a parabolic mirror, you'd have to take the 'beam deviation factor' (BDF) into account, for the finding of the center of the offset focal cloud.
This BDF seems to be about 0.9 according to some literature on the internet; so an offset mounted LNB can be about 1.1 times further from the center than calculated with the rule 'angle of incidence = angle of reflection'.
I never tested this myself, but I believe it to be true.
By the way. For the angle between satellites, the difference of 'azimuth values' is not the proper value to calculate with, though some people/calculators do that.
This can be easily seen when you are near the equator, and when you calculate the angle between a satellite just east of your due south(north), and a satellite just west of your due south(north). Though the receiving angle between these two satellites is small, the azimuth difference is near 180 degrees....!
So that angle calculation should be done differently.
Greetz,
A33