I dont know the exact focal point of your dish but if its around 48 inches the separation should be about 5 inches apart on those LNBs.
tune the dish for the weaker sat being centered and move the other LNB that much off center.
the off center one will be a weaker signal by a few points and you may have to play with the focal depth and the tilt of the LNB a slight amount to peak it.
But Yes it can work.
KU Band or C-Band? This was in the C-Band area but you mention KU Band
I tried 99/95 C-Band on a 6 footer and failed miserably.....could get 95 good and the really strong stuff on 99 (WHT) very low.
just so you know when you add the 2nd LNB its bass ackwards from how they are in the sky. So if you stand in front of the dish facing it and the dish is at 99W the 2nd LNB will be to the LEFT of the existing LNB